Photochemical decarbonylation of cyclic ketones in solution: evidence for a biradical intermediate in the pyranosidulose–furanoside conversion
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1261-1262
- https://doi.org/10.1039/c29700001261
Abstract
The photolyses of pure pyranosiduloses (1) and (2) afford decarbonylated compounds (3), (4), and (5) in the same ratios, suggesting that they are formed via a common stabilised biradical (6).Keywords
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