The Rhodium Carbenoid Route to Cyclic Ethers. Synthesis of thecis-2,7-Disubstituted Oxepane Skeleton of Isolaurepinnacin
- 1 January 1990
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1990 (02) , 95-96
- https://doi.org/10.1055/s-1990-20998
Abstract
The cis-2,7-disubstituted oxepane skeleton 1 of the marine natural product isolaurepinnacin is obtained by two routes, both of which involve a rhodium (II) acetate mediated cyclisation of a diazoalcohol to give a functionalised oxepane, suitable for further elaboration.Keywords
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