An Improved Procedure for the Pd(II)-Catalyzed Claisen Rearrangement via In Situ Enol Ether Exchange

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Abstract
The title rearrangement, when carried out using CF3CO2H as a co-catalyst, is shown to proceed at room temperature to afford the Claisen product with a high level of both diastereoselection and asymmetric transmission. The scope and limitation of the new procedure are defined.

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