Functionalisation of saturated hydrocarbons. Part 1. Some reactions of a ferrous chloride–chloramine-T complex with hydrocarbons
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 445-451
- https://doi.org/10.1039/p19830000445
Abstract
The reactions of several hydrocarbon substrates with a ferrous chloride–chloramine-T complex, generated in situ, have been studied. Tosylamination of adamantane and chlorination of mesitylene proceed in good yield while naphthalene gives N,N′-bis(toluene-p-sulphonyl)-1,4-naphthoquinone di-imine. A variety of olefinic substrates undergo both cis- and trans-addition to the double bond as well as allylic functionalisation.Keywords
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