Synthetic Studies of Halichondrin B, an Antitumor Polyether Macrolide Isolated from a Marine Sponge. 3. Synthesis of C27-C36 SubunitviaCompletely StereoselectiveC-Glycosylation to the F Ring
- 1 January 1994
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1994 (01) , 43-45
- https://doi.org/10.1055/s-1994-22732
Abstract
A stereoselective synthesis of the C27-C36 fragment of halichondrin B starting from L-tartaric acid using an efficient acidcatalyzed C-glycosylation to the F ring as the key step is reported.Keywords
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