Correlation and Negative Continuum Effects for the RelativisticTransition in Two-Electron Ions using the Multiconfiguration Dirac-Fock Method
- 14 October 1996
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 77 (16) , 3323-3326
- https://doi.org/10.1103/physrevlett.77.3323
Abstract
The role of the continuum and of correlation in the multiconfiguration Dirac-Fock calculation of nondiagonal one-electron operators is described. Because of its importance and symmetry which emphasize both effects, we study the relativistic transition in two-electron ions. It is shown that both contributions have the same magnitude, and must be included even at low . These contributions improve significantly the agreement between theory and experiment at all , reducing the disagreement for Nb from to times the experimental error.
Keywords
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