Linear dependence of spin exchange coupling constant on bridge angle in phenoxy-bridged dinickel(II) complexes
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 1337-1338
- https://doi.org/10.1039/c39940001337
Abstract
A magneto-structural relationship showing linear dependence of antiferromagnetic exchange coupling constant (–J) on Ni–O–Ni bridge angle as well as the intramolecular Ni ⋯ Ni distance has been obtained with a series of phenoxy-bridged macrocyclic dinickel(II) complexes with centrosymmetric structures.Keywords
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