Selection rules for optical activity and linear birefringence bilinear in electric and magnetic fields
- 14 February 1989
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic, Molecular and Optical Physics
- Vol. 22 (3) , 459-473
- https://doi.org/10.1088/0953-4075/22/3/011
Abstract
All independent geometric factors are derived for the possible polarisation dependence of optical activity and linear birefringence effects bilinear in a static electric and magnetic field, for fluids. The extension to oriented systems is illustrated. Differences between the methods used and results obtained with those of earlier workers are noted and where possible resolved. Several optical effects predicted to exist by earlier workers are shown to be forbidden, and vice versa. In particular the Jones birefringence should appear in E1/M1 coupling for all fluids, irrespective of the centrosymmetric or non-magnetic character of the system, and there exist field-dependent refractive index contributions which reverse with the direction of the light beam and are detectable by a ring laser.Keywords
This publication has 19 references indexed in Scilit:
- Molecular structure and chiralityJournal of Chemical Education, 1987
- Change in chiroptical properties caused by intermolecular couplingProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1987
- Fundamental symmetry aspects of chiralityBiosystems, 1987
- True and false chirality and parity violationChemical Physics Letters, 1986
- Symmetry restrictions for natural and induced circular dichroism and optical activity for all point groupsJournal of Physics C: Solid State Physics, 1982
- Radiation–Molecule Interactions in Chemical PhysicsPublished by Elsevier ,1982
- Phonon Raman spectroscopy in systems with electronic degeneracyJournal of Physics C: Solid State Physics, 1981
- A molecular theory of new differential light-scattering effects in a fluidProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1981
- Electric circular dichroismChemical Physics, 1978
- New electro-optical and magneto-optical effects in liquidsSoviet Physics Uspekhi, 1977