Synthesis and X-ray crystal structure of cyclooctatetraenyllanthanide alkyl complexes [Li(thf)2{µ-(η2:η8-C8H8)}Ln{CH(SiMe3)2}2](Ln = Y, Sm, Lu; thf = tetrahydrofuran)
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 623-625
- https://doi.org/10.1039/c39930000623
Abstract
The metathetic reaction [Ln(η8-C8H8)(µ-Cl(thf)]2(Ln = Y, Sm, Lu) with LiCH(SiMe3)2results in the formation of the Cyclooctatetraenyllanthanide alkyl complexes [Li(thf)2{µ-+(η2;η8-C8H8)} Ln{CH (SiMe 3)2}2](Ln = Y1a, Sm1b, Lu1c); 1b has been structurally characterized by X-ray crystallography.Keywords
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