The red form of [Re(phen)(CO)3(H2O)]CF3SO3.H2O
- 15 June 1999
- journal article
- Published by International Union of Crystallography (IUCr) in Acta Crystallographica Section C Crystal Structure Communications
- Vol. 55 (6) , 913-916
- https://doi.org/10.1107/s0108270199001432
Abstract
The coordination geometry of the cations in the red form of aquatricarbonyl(1,10-phenanthroline-N,N')rhenium(I) trifluoromethanesulfonate hydrate, [Re(C12H8N2)(CO)3-(H2O)]CF3SO3.H2O, is approximately octahedral, with a facial arrangement of the linearly coordinated carbonyl ligands. The phenanthroline (phen) ligands interleave to form a columnar pi-stacked structure.Keywords
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