Hydroboration of N-allyl derivatives of pyrrolidine, piperidine, hexahydroazepine and morpholine

1 January 1982

journal article
Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications

Vol. 47 (8) , 2150-2156
https://doi.org/10.1135/cccc19822150

Abstract

Heating of allyl derivatives I with triethylamine-borane gave spirocyclical amine-boranes II, which were hydrolysed with hydrochloric acid to hydrochlorides of aminoboronic acids, III. Oxidation of these hydrochlorides produced amino alcohols IV.

Keywords

ALLYL DERIVATIVES
HEATING
AMINE BORANES
TRIETHYLAMINE BORANE
AMINO ALCOHOLS
AMINOBORONIC ACIDS
HYDROCHLORIDES PRODUCED

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