Electronic structure contributions to electron transfer in blue Cu and CuA
- 1 February 2000
- journal article
- review article
- Published by Springer Nature in JBIC Journal of Biological Inorganic Chemistry
- Vol. 5 (1) , 16-29
- https://doi.org/10.1007/s007750050003
Abstract
Centers are summarized and their relation to intra- and inter-protein electron transfer (ET) kinetics are described. Specific contributions of the electronic structures of these two broad classes of Cu ET proteins to HAB, λ, and ΔE° are discussed. Also, the role of the protein structure in determining key geometric features which define the electronic structures of the metal sites in these proteins is considered.Keywords
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