Highly stereocontrolled reduction of an alkynyl ketone possessing a 1,3-dithianyl moiety using oxazaborolidine–BH3
- 1 October 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 20,p. 2519-2520
- https://doi.org/10.1039/b107604c
Abstract
Highly enantioselective reduction of 2-benzyl-2-propioloyl-1,3-dithiane was conducted using oxazaborolidine derived from L-threonine and borane complex to give (S)-2-benzyl-2-(1-hydroxyprop-2-ynyl)-1,3-dithiane in high enantiomeric purity.Keywords
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