Volatility Studies of Metal Chelates. IV*Thermal Behaviour of Copper(II) Chelates of Aryl β-Diketones
- 1 January 1979
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 32 (2)
- https://doi.org/10.1071/ch9790277
Abstract
The thermal stability and volatility of the copper (II) chelates of 38 aryl β-diketones have been examined by combined thermogravimetry and differential thermal analysis. Volatility is characterized by fluorine substitution (in R and R' of RCOCH2COR?), particularly in the alkyl (R) moiety of the β-diketone. When chlorine, bromine and methyl substituents are introduced into the aromatic ring (R'), there is a significant reduction in volatility. If R is CH3, thermal stability is markedly affected, especially when R' is C6F5.Keywords
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