Selective Nucleophilic Openings Of 2,3-Epoxy Alcohols Catalysed By Pd(Pph3)4
- 1 August 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (15) , 2313-2317
- https://doi.org/10.1080/00397919008053174
Abstract
Selective nucleophilic openings of 2, 3-epoxy alcohols with high regie selectivity by various nucleophiles in the presence of Pd(PPh3)4 catalyst for the first time is described.Keywords
This publication has 9 references indexed in Scilit:
- Two new asymmetric epoxidation catalysts. Unusual stoichiometry and inverse enantiofacial selectionThe Journal of Organic Chemistry, 1984
- On the mechanism of titanium-tartrate catalyzed asymmetric epoxidationPure and Applied Chemistry, 1983
- Mechanism and Stereoselectivity of Asymmetric HydrogenationScience, 1982
- Regio- and stereoselective ring opening of epoxy alcohols with organoaluminium compounds leading to 1,2-diolsTetrahedron Letters, 1982
- The first practical method for asymmetric epoxidationJournal of the American Chemical Society, 1980
- Palladium catalyzed oxidations of secondary alcoholsTetrahedron Letters, 1979
- .beta.,.gamma.-Unsaturated diazo ketones. A new initiator for polyolefinic cationic cyclizationThe Journal of Organic Chemistry, 1977
- Reduction of epoxides. IV. Lithium aluminum hydride reduction of cyclohexene oxide containing neighboring oxygen groupsThe Journal of Organic Chemistry, 1972
- Studies on epoxides. Part II. Abnormal lithium aluminium hydride reduction of cis 3,4-epoxy-5-hydroxycholestanesTetrahedron Letters, 1967