Preparation of a New Class of C2-Symmetric Chiral Phosphines: The First Asymmetric Staudinger Reaction
- 1 January 1990
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1990 (04) , 199-200
- https://doi.org/10.1055/s-1990-21032
Abstract
The synthesis of the first C2-symmetric phospholane, (2R,5R)-1-phenyl-2,5-dimethylphospholane (10), and its use in an enantioselective Staudinger reaction (reduction of azides with phosphines) is reported.Keywords
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