Branching of Ketosugars by Ethyl Trimethylsilyl-Acetate/Tetra-n-Butylammonium Fluoride
- 1 March 1986
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 5 (1) , 77-82
- https://doi.org/10.1080/07328308608082644
Abstract
Hexopyranose- and hexofuranose-uloses, on treatment with ethyl trirnethylsilylacetate/tetra-n-butylammohium fluoride, form β-hydroxy esters or derivatives thereof instead of their TMS-enol ethers. 29Si NMR studies confirm the proposed mechanism.Keywords
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