Redox tuning of the dimolybdenum compounds at the ligand periphery: a direct correlation with the Hammett constant of the substituents
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 2257-2258
- https://doi.org/10.1039/c39950002257
Abstract
Oxidation potentials Of [Mo2(ArNCHNAr)4](Ar = aryl), a direct measure of the HOMO (δ orbital) energy, correlate with the Hammett constant of aryl substituents, while both structural and spectroscopic data indicate that the valence structure around the dinuclear core is unperturbed.This publication has 0 references indexed in Scilit: