Highly Enantioselective Transfer Hydrogenation of α,β-Unsaturated Ketones
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- 21 September 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (41) , 13368-13369
- https://doi.org/10.1021/ja065708d
Abstract
We describe an efficient and highly enantioselective conjugate transfer hydrogenation of α,β-unsaturated ketones that is catalyzed by a salt made from tert-butyl valinate and a recently introduced powerful chiral phosphoric acid catalyst (TRIP).Keywords
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