Effect of static correlations on the pair friction coefficient
- 15 November 1980
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 73 (10) , 5254-5258
- https://doi.org/10.1063/1.439953
Abstract
A calculation of the spatial dependence of the pair friction tensors ζij(r12), (i, j=1,2) for two hard sphere solute particles in a hard sphere fluid is presented. The calculation is based on a kinetic theory expression for the pair friction tensor. The contribution from dynamically uncorrelated collisions is computed here. (We do not consider the contribution from correlated collisions, which are important at high density.) The friction tensor is found to have a significant dependence on the solute pair separation, which arises from static correlations among the bath and solute particles.Keywords
This publication has 7 references indexed in Scilit:
- Microscopic theory of condensed phase chemical reactions. II. Configuration space equationsThe Journal of Chemical Physics, 1980
- Microscopic theory of condensed phase chemical reactions. I. Pair phase space kinetic equationThe Journal of Chemical Physics, 1980
- Equilibrium Theory of Simple LiquidsPhysical Review A, 1972
- On the Equation of State of the Rigid-Sphere FluidThe Journal of Chemical Physics, 1965
- The triplet distribution function in a fluid of hard spheresMolecular Physics, 1963
- Note on the Theory of Diffusion Controlled Reactions : Application to Photodissociation in SolutionThe Journal of Chemical Physics, 1956
- Diffusion-controlled reaction ratesJournal of Colloid Science, 1949