A Study of theX2Σ Potential Energy Curve of the Gaseous Calcium Chloride Molecule
- 1 January 1980
- journal article
- Published by IOP Publishing in Physica Scripta
- Vol. 22 (3) , 221-223
- https://doi.org/10.1088/0031-8949/22/3/007
Abstract
Different models describing ionic potential energy curves have been fitted to a RKR potential derived from the twelve lowest vibrational levels of the X2 Σ+ state in CaCl. The effect of covalent influence in the bond was studied. It turns out that the dissociation energies as well as the polarizabilities of the singly charged ions are well determined from the observed Bv and Tv values.Keywords
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