Solid-state dye lasers based on modified rhodamine 6G dyes copolymerized with methacrylic monomers

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Abstract
Modified rhodamine 6G molecules with polymerizable double bonds have been copolymerized with methacrylic monomers and the resulting polymers have been pumped at 337 nm with a N2 laser in a transversal configuration. The preparation of these new materials is described in detail and their lasing properties are evaluated. Important increases in photostability, with lasing efficiencies similar to those found for the parent dye rhodamine 6G in ethanol solution, have been obtained for some of these materials. Lifetimes (measured as an 80% efficiency drop) in excess of 20 000 shots at repetition rates of 2 Hz have been demonstrated. Strong dependence on pump repetition rate was observed. Possible mechanisms and processes responsible for the behavior of these materials are discussed. By using a rotating system where the sample is scanned in a continuous way, the laser output remained stable, with no sign of degradation, after 500 000 shots.