Synthesis and X-ray structure of bis(trifluoromethyl)(N,N-diethyldithiocarbamato)-copper; a remarkably stable perfluoroalkylcopper(III) complex
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1633-1634
- https://doi.org/10.1039/c39890001633
Abstract
The reaction between trifluoromethylcadmium reagent and Br2Cu(edtc)(edtc =N,N-diethyldithiocarbamato) or CdI+[(CF3)2Cu]– with [Et2NC(S)S]2 in DMF (dimethylformamide) at –30°C yields the stable CuIII perfluoroalkylcopper complex, (CF3)2CuSC(S)NEt2.Keywords
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