A CONVENIENT SYNTHESIS OF (TRICHLOROMETHYL)CHLOROSILANES
- 5 June 1980
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 9 (6) , 721-724
- https://doi.org/10.1246/cl.1980.721
Abstract
In the presence of a catalytic amount of triphenylphosphine, 1,1,2,2-tetrachloro-1,2-dimethyldisilane reacted smoothly under mild conditions with carbon tetrachloride to produce (trichloromethyl) methyldichlorosilane 1 in good yield. (Trichloromethyl)dimethylchlorosilane was also readily prepared by the triphenylphosphine-promoted transfer of the trichloromethyl group from 1 to dimethyldichlorosilane.This publication has 14 references indexed in Scilit:
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