1,2-Stereoinduction in β-Oxy-Radicals: The Influence of the α-Substituent
- 1 January 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (01) , 116-118
- https://doi.org/10.1055/s-1995-4867
Abstract
1,2-Stereoinduction is studied in H-abstraction reactions of acyclic radicals with a methyl and a tert-butyldiphenylsiloxy group at the stereogenic center. The extent of the stereoselectivity depends significantly upon the substituent at the radical center.Keywords
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