Schiff Base Complexes of Dioxouranium(VI), II Dioxouranium(VI) Complexes of the Schiff Bases of o-Hydroxy Acetophenone, 2,4-Pentandione and Salicylaldehyde
Open Access
- 1 January 1976
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 31 (1) , 22-28
- https://doi.org/10.1515/znb-1976-0104
Abstract
Dioxouranium(VI) derivatives of the type UO2(NO3)2(SBH2)2 have been synthesised by the reactions of dioxouranium(VI) nitrate hexahydrate with the nitrogen donor ligands (SBH2) in 1: 2 molar ratio. The Schiff bases used in these reactions are of the general type, o-HOC6H4C(CH3): NX1OH (where X1 = -CH2CH2-, -CH2CH(CH3)- and -CH2CH2CH2-), CH3C(OH)CHC(CH3): NX2OH and o-OHC6H4CH: NX2OH (where X2 = -CH2CH2-, -CH2CH(CH3)-, -CH2CH2CH2- and o-C6H4). The resulting new derivatives have been characterized on the basis of elemental analysis, magnetic susceptibility, conductance measurements and infrared spectraKeywords
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