A dimeric quadruply metal–metal bonded molybdenum(II)–Schiff's base complex: bis[N,N′-ethylenebis(acetylacetoneiminato)molybdenum(II)]
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 350-351
- https://doi.org/10.1039/c39880000350
Abstract
Reduction of dichloro-N,N′-ethylenebis(acetylacetoneiminato)molybdenum(IV), [Mo(acacen)Cl2], with sodium in the presence of diphenylacetylene afforded the diamagnetic dimer [Mo(acacen)]2 containing an Mo–Mo quadruple bond [Mo–Mo, 2.1678(4)Å], as shown by an X-ray crystal structure determination.Keywords
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