Magnetic properties and crystal structure of the p-fluorophenyl nitronyl nitroxide radical crystal: ferromagnetic intermolecular interactions leading to a three-dimensional network of ground triplet dimeric molecules
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 4 (8) , 1219-1226
- https://doi.org/10.1039/jm9940401219
Abstract
The crystal of p-fluorophenyl nitronyl nitroxide [2-(4-fluorophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide, abbreviated as p-FPNN] radical has been found to possess a dimeric structure. Each dimer is related to adjacent ones by four-fold screw symmetry to form a three-dimensional network. The temperature dependence of the paramegnetic susceptibility is explained by the formation of a triplet state within the dimer and additional interdimer ferromagnetic interactions. The intra- and inter-dimer exchange interactions are estimated to be J/kB= 5.0 K and J′/kB= 0.02 K, respectively. The molecular arrangement in the dimer suggests that the intermolecular interactions between the NO group and the phenyl ring are favourable to ferromagnetic coupling. Slight structural changes below ca. 100 K have been studied by use of electron paramagnetic resonance and powder X-ray diffraction measurements.Keywords
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