Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 10,p. 1172-1176
- https://doi.org/10.1039/p19770001172
Abstract
Reactions of trialkylboranes (R2 3B) with 1-lithio-1,1-bis(phenylthio)alkanes [R1(PhS)2C–Li+; R1= H or Prn], followed by reaction with mercury(II) chloride and oxidative work-up, give high yields of secondary (R1= H) or tertiary (R1= Prn) alcohols (R1R2 2COH).Keywords
This publication has 0 references indexed in Scilit: