Nonadiabatic Effects in the Internal Rotation of ·CH2COO− in Irradiated Zinc Acetate Dihydrate
- 15 December 1970
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 53 (12) , 4466-4469
- https://doi.org/10.1063/1.1673974
Abstract
The article of record as published may be found at http://dx.doi.org/10.1063/1.1673974The EPR spectrum of the • CH2Coo- radical in a single crystal host displays nonadiabatic motional effects. A phenomenological theory is suggested, based on the density matrix of the spin system, and a technique is described for rapid calculation of simulated spectra.Office of Naval ResearcKeywords
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