Condis‐crystal structure of flexible‐chain polymers in polymer blends

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Abstract
When heated above the melting point, a thermodynamic equilibrium mesophase of conformationally disordered crystal type (so‐called condis state) has been found in some flexible‐chain polymers (not containing mesogenic groups) dispersed in a matrix of another polymer. Typical organic and inorganic polymers such as polyethylene (PE) and poly[bis (2, 2, 2‐trifluoroethoxy) phosphazene] (PPh) were taken as main components of the polymer blends under investigation. The most interesting situation is realized if two mesophase polymers are used in the same binary blend.

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