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Isotope effect on the coupling constant
1
J(
13
C–H)
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Publications
Isotope effect on the coupling constant
1
J(
13
C–H)
Isotope effect on the coupling constant
1
J(
13
C–H)
NS
Nickolay M. Sergeyev
Nickolay M. Sergeyev
VS
Vitalii N. Solkan
Vitalii N. Solkan
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1 January 1975
journal article
Published by
Royal Society of Chemistry (RSC)
in
Journal of the Chemical Society, Chemical Communications
No. 1
,
p.
12-13
https://doi.org/10.1039/c39750000012
Abstract
The negative isotope effect on the coupling constant
1
J
(
13
C–H){Δ
J
=(
γ
H
/
γ
D
)[
1
J
(
13
C–D)]–
1
J
(
13
C–H)} has been confirmed by INDO FP calculations of the
1
J
(
13
C–H) coupling constant in methane by varying one of the C–H distances.
Keywords
ISOTOPE EFFECT
COUPLING CONSTANT
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