Shell effects on symmetric fragmentations of alkali-metal clusters
- 1 August 1990
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 42 (4) , 2267-2278
- https://doi.org/10.1103/physreva.42.2267
Abstract
The process of symmetric fragmentation of multiply charged alkali-metal clusters consisting of several tens of atoms is studied using the theory of shell corrections, which has been originally applied to the nuclear fission problem. The potential-energy surface of the fragmentation process is calculated for various sizes of clusters. The variation of the shell correction term due to shape deformation is found to be much larger than that of the energy of the liquid droplet if the mother cluster is metastable. Symmetric fragmentation is most likely to occur when the size of products is nearly equal to the magic number. The reaction paths of fragmentation into both magic and nonmagic clusters are also discussed.Keywords
This publication has 25 references indexed in Scilit:
- Abundance of Na cluster ions ejected from a liquid metal ion sourceThe European Physical Journal D, 1989
- Dissociation channels of multiply charged van der Waals clustersPhysical Review A, 1988
- Systematicab initioconfiguration-interaction study of alkali-metal clusters. II. Relation between electronic structure and geometry of small sodium clustersPhysical Review B, 1988
- Systematicab initioconfiguration-interaction study of alkali-metal clusters: Relation between electronic structure and geometry of small Li clustersPhysical Review B, 1987
- Effects of electron correlation and geometrical structure on stability of metal clustersPhysical Review B, 1986
- Ellipsoidal shell structure in free-electron metal clustersPhysical Review B, 1985
- Electronic shell structure in potassium clustersSolid State Communications, 1985
- Electronic and structural properties of sodium clustersPhysical Review B, 1985
- Electronic Shell Structure and Abundances of Sodium ClustersPhysical Review Letters, 1984
- Production of large sodium clusters (Nax,.x⩽65) by seeded beam expansionsChemical Physics Letters, 1982