(Invited) Solution Growth of II–VI Compounds

Abstract
Crystal growth of Zn and Cd chalcogenides from a variety of solutions has been studied. Solutions investigated included Te, Se, Te–Se mixture and As2Se3. Te corner in the Zn–Se–Te ternary phase diagram has been determined. High quality ZnSe crystals have been grown from Se solution, and also from As2Se3. Phosphorus doped ZnSe was grown from (As2Se3 + P) solution. A shallow acceptor related to phosphorus hasbeenestimated to be (84±4 meV). Thinlayers of ZnSe were grown on ZnS and ZnTe substrates by liquid-phase epitaxial technique utilizing Te or Te–Se as solvents.

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