Enthalpies of solution and single ion enthalpies of transfer from water to dioxane–water mixtures
- 15 November 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (22) , 3487-3491
- https://doi.org/10.1139/v76-501
Abstract
Standard enthalpies of solutions of sodium bromide, potassium bromide, tetrabutyl phosphonium bromide, tetraphenyl phosphonium bromide, and sodium tetraphenyl boron have been measured in 20%, 44.5%, and 64.5% dioxane–water mixture. On the extra thermodynamic assumption ΔΔHs(Ph4P+) = ΔΔHs(−BPh4) single ion enthalpies of transfer from water to dioxane–water mixtures have been calculated for various ions.Keywords
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