Vibrational predissociation spectra of (HF)n, n = 2–6
- 1 November 1981
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 75 (9) , 4733-4734
- https://doi.org/10.1063/1.442593
Abstract
Using molecular beam techniques and a tunable infraredlaser, the vibrational predissociation spectra for (HF)n, n = 2 to 6, in the 3000 to 4000 cm−1 range are presented. The vibrational bands have been assigned to intramolecular HF stretching modes and combinations of intra- and intermolecular modes. The structures of (HF)n, n = 3 to 6, were found to be cyclic, i.e., each HF molecule is both a proton donor and acceptor.Keywords
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