Unusual bonding patterns in halogen-substituted η5-cyclopentadienyl metal derivatives. The crystal and molecular structure of η5-pentachlorocyclo-pentadienylcyclo-octadienerhodium
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 403-404
- https://doi.org/10.1039/c39750000403
Abstract
Localized bonding has been observed in the η5-C5Cl5 ring of the title compound which suggests appreciable contribution from a bonding model where the ring is bonded to the metal by two olefin π-bonds and one σ-alkyl bond.Keywords
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