Pre-isoflavonoid stages in the biosynthesis of amorphigenin: ring-D formation and ring-A migration
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1063-1065
- https://doi.org/10.1039/c39860001063
Abstract
Despite low incorporations of doubly labelled [13C]acetate during the biosynthesis of amorphigenin by Amorpha fruticosa seedlings, it has been possible to solve the ring-D folding by an INADEQUATE n.m.r. experiment; new proposals are made for the mechanism of the enzyme catalysed flavanone–isoflavone transformation step.Keywords
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