Evidence for formation of a [TlOH]+ complex
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 387-388
- https://doi.org/10.1039/c39750000387
Abstract
Using pulse radiolysis with conductivity and spectrophotometry as a detection system evidence was found for the formation of the monocharged complex [TlOH]+ which is in equilibrium with Tl2+(pK 4·6 ± 0·2); k(H++[TlOH]+) and k(Tl2++ H2O) are 1·4 (±0·5)× 1010 l mol–1 s–1 and 3·5 × 105 s–1 respectively.Keywords
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