Mechanism of hydrogen transfer in the reduction of the imine bond by an NADH model. Use of cyclopropane ring as a chemical probe
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 149-150
- https://doi.org/10.1039/c39830000149
Abstract
Reduction of N-cyclopropylmethylenephenylamine by 3,5-diethoxycarbonyl-2,6-dimethyl-1,4-dihydropyridine (Hantzsch ester) results in the exclusive formation of N-cyclopropylmethylaniline, whereas reduction with triphenyltin hydride gives both N-cyclopropylmethylaniline and n-butylaniline, a product of cyclopropane ring cleavage.Keywords
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