Formation of α-dimethylamino-α-methylthio-carbene. Carbene-induced isomerization of dimethyl maleate
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 907-908
- https://doi.org/10.1039/c29700000907
Abstract
Deprotonation of (Me2N)(MeS)CH+I– with NaH produces an N,S-carbene: dimethyl maleate undergoes isomerization during the carbene-forming reaction.Keywords
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