Tetrahydroborate complexes of uranium with 2-(diphenylphosphino)pyridine
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 533-534
- https://doi.org/10.1039/c39840000533
Abstract
U(BH4)3(THF)x, (THF = tetrahydrofuran,) and (η5-C5H5)UCl3 react with 2-(diphenylphosphino)pyridine, (Ph2Ppy), producing 1:2 and 1:1 adducts, respectively; and X-ray crystal structure of U(BH4)3(Ph2Ppy)2·1/2C6H6 shows U–P = 3.162(1) and U–N = 2.659(4)Å.Keywords
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