Facile Synthesis of Alkenylsilanes from Organic Halides and Vinylsilanes in the Presence of Triethylamine and Palladium Catalysts
- 1 December 1990
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 19 (12) , 2175-2176
- https://doi.org/10.1246/cl.1990.2175
Abstract
Organic halides such as PhI, ArBr, and β-bromostyrene reacted with di- or monochlorovinylsilanes or triethoxyvinylsilane in the presence of triethylamine and palladium catalysts to give β-substituted vinylsilanes in excellent to moderate yields.Keywords
This publication has 3 references indexed in Scilit:
- Polymeric Organosilicon SystemsJournal of Organometallic Chemistry, 1989
- Synthesis of 1-trimethylsilyl 1,3-dienes by the palladium-catalyzed reaction of trimethylvinylsilane with vinyl iodides/silver nitrate or vinyl triflatesThe Journal of Organic Chemistry, 1988
- Synthesis of (E)-(2-arylethenyl)silanes by palladium-catalyzed arylation of vinylsilanes in the presence of silver nitrateThe Journal of Organic Chemistry, 1986