Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum–thallium complex, [MoTl(SC₆F₅)₄(η-C₅H₅)]

1 January 1983

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 8,p. 452-453
https://doi.org/10.1039/c39830000452

Abstract

Paramagnetic diene complexes [MoX₂(diene)(η-C₅H₅)](X = Cl, Br, I, SAr) give well resolved e.s.r. spectra in solution; reaction with TISC₆F₅ produces the unusual fluxional, bimetallic complex [MoTl(SC₆F₅)₄(η-C₅H₅)].

Keywords

III
MOLYBDENUM
DIENE COMPLEXES
FLUXIONAL
E.S.R
GIVE
TISC6F5
DIAMAGNETIC
SPECTRA

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Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum–thallium complex, [MoTl(SC6F5)4(η-C5H5)]

Abstract

Keywords

Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum–thallium complex, [MoTl(SC₆F₅)₄(η-C₅H₅)]