Enzyme-catalysed baeyer–villiger oxidations of some substituted bicyclo[3.2.0]heptanones
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1438-1439
- https://doi.org/10.1039/c39900001438
Abstract
The ketones 1 and 4 are oxidized to γ-lactones 2 and 5 with low enantioselectivity by both Acinetobacter sp. NCIB 9871 and Pseudomonas sp. NCIB 9872; in contrast the ketones 7 and 10 are biotransformed to products 8/9 and 11 respectively of very high optical purity.Keywords
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