Enantiomer separation using mobile and immobile cyclodextrin derivatives with electromigration
- 1 January 1994
- journal article
- research article
- Published by Wiley in Electrophoresis
- Vol. 15 (1) , 835-841
- https://doi.org/10.1002/elps.11501501118
Abstract
The principle of electrochromatography is applied to enantiomer separation with wall‐coated capillaries of 50μm (ID). As chiral stationary phase an immobilized polysiloxane containing chemically bonded monokis‐6‐O‐octamethylene‐permethyl‐cyclodextrin (β‐ or γ‐Chirasil‐Dex) was used. The results are compared with the conventional method of adding cyclodextrin derivatives as chiral pseudostationary phase to the running buffer.Keywords
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