Silicon in synthesis. Methoxymethyltrimethylsilane, a new reagent for reductive nucleophilic acylation
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 822-823
- https://doi.org/10.1039/c39790000822
Abstract
Lithium methoxy(trimethylsilyl)methylide (6), prepared by deprotonation of methoxymethyltrimethyl-silane (3) using s-butyl-lithium reacts with ketones and aldehydes to give adducts (7b)–(9b) that can be converted into aldehydes.Keywords
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