Vierzig Jahre „penta-ammine effect” / Forty Years of Penta-ammine Effect
Open Access
- 1 June 1973
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 28 (5-6) , 282-286
- https://doi.org/10.1515/znb-1973-5-612
Abstract
The actual aspect of knowledge on the state of copper ammine complexes in aqueous solution was discussed. It was concluded, that the Cu(II)-ion has the coordination number of 5 contrary to the value of 6 assumed today. The structure of CuN5-chromophores in aqueous solution indicate, that the development of the penta-ammine effect is based on their higher ligand fields symmetries forced by formation of CuN5-chromophores comparised with CuN4-chromophores.Keywords
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