Cationic carbene complexes of nickel(II)
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 899-900
- https://doi.org/10.1039/c39750000899
Abstract
The nickel acetylide (1) reacts with alcohols in the presence of perchloric acid to give stable cationic alkoxy-carbene complexes (2), the 1H n.m.r. spectra of which show the presence of two conformational isomers; deprotonation with triethylamine occurs at the carbene methyl group.Keywords
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