Reactions of chlorine trifluoride with pentafluoroiodobenzene and related compounds. Preparation of pentafluorophenyliodine(V) tetrafluoride
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 509-511
- https://doi.org/10.1039/dt9740000509
Abstract
Pentafluoroiodobenzene is oxidised by chlorine trifluoride below room temperature to pentafluorophenyliodine(V) tetrafluoride and C6F4(IF4)2 is one of the products from the oxidation of 1,4-I2C6F4 under similar conditions. Bromopentafluorobenzene is not oxidised by ClF3 but addition of chlorine and fluorine to the ring occurs. Similar behaviour is observed with C6F5IF4 and ClF3.Keywords
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